Excitation of electronic states of Ar, H(2), and N(2) by positron impact.
نویسندگان
چکیده
We have measured the first state-resolved, absolute cross sections for positron excitation of electronic states of an atom or molecule using a high resolution (Delta E approximately 25 meV FWHM) beam of positrons from a Penning-Malmberg trap. We present cross sections for the excitation of the low-lying levels of Ar, H(2), and N(2) for incident positron energies between threshold and 30 eV. For Ar and H2, comparison can be made with theoretical calculations, and, in the case of H(2), the results resolve a significant discrepancy between the only two available calculations.
منابع مشابه
Electronic effects on singlet-triplet energy splittings in aryl-cyclopentadienylidenes
Energy gaps, AXsar (X=E, H and G) (AX.,.,-=lia,„,,,InrX“dpka,) between single (s) and triplet (I) states werecalculated at B3LTP/6-3 I 1.HO" level of theory. Our results showed that electron donating substituents(G = -NHz, -OH. -CH), -F, -Cl and -Br) at phenyl group cause to increase and electron withdrawingsubstiluents (G -CF2. and -NO:) lead to decrease the singlet-triplet energy gaps of Ar -...
متن کاملDemonstration of a diode-pumped metastable Ar laser.
Pulsed lasing from optically pumped rare gas metastable atoms (Ne, Ar, Kr, and Xe) has been demonstrated previously. The laser relies on a three-level scheme, which involves the (n+1)p[5/2](3) and (n+1)p[1/2](1) states from the np(5)(n+1)p electronic configuration and the metastable (n+1)s[3/2](2) level of the np(5)(n+1)s configuration (Racah notation). Population inversions were achieved using...
متن کاملElectronic effects at 2 and 7 α–position of divalent unsaturated seven membered ring R2C6H6M (M=C, Si, Ge, Sn, Pb)
Electronic effects were investigated on the singlet–triplet energy gaps of divalent unsaturated seven- membered ring R2C6H6M (M=C, Si, Ge, Sn, Pb, R= –H, -CH3, i-Pr , t-Bu) at B3LYP/6-311++G** level. All the triplet states of R2C6H6C were more stable than the related the singlet states while all the singlet states of R2C6H6M (M= Si, Ge, Sn, Pb, R= –H, -CH3, i-Pr , t-Bu) were more stable than th...
متن کاملمحاسبه سطح مقطع جزئی و کل در تقریب مرتبه دوم بورن- فادیف در برخورد پوزیترون با اتم هیدروژن در کانال تهییج
In this paper, we have implemented a three-body formalism, where the interaction potential is replaced by the transition matrix, in the excitation channel for the collision of positron and atomic hydrogen. Differential and total cross sections are calculated while the first and second order terms of the FWL (Faddeev-Watson-Lovelace) series in the transition from ground state to the first excite...
متن کاملPositron-impact ionization, positronium formation, and electronic excitation cross sections for diatomic molecules
Absolute measurements are presented for the positron-impact cross sections for positronium formation, direct ionization, and total ionization of the diatomic molecules N2, CO, and O2, in the range of energies from threshold to 90 eV. Cross sections for the electronic excitation of the a 1 and a 1 state in N2 and the A 1 state in CO near threshold are also presented. The experiment uses a cold, ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Physical review letters
دوره 87 7 شماره
صفحات -
تاریخ انتشار 2001